EPA Final Rule:

Amendments to Standards of Performance for New Stationary Sources; Monitoring Requirements

(40 CFR Part 60)

 January 12, 2004

[69 FR 1785]

EPA has finalized its Performance Specification 11 (PS-11): Specifications and Test Procedures for Particulate Matter (PM) Continuous Emission Monitoring Systems (CEMS) at Stationary Sources and Monitoring Requirements; and Procedure 2: Quality Assurance Requirements for PM CEMS at Stationary Sources.  The final rule is available at EPA’s Technology Transfer Network at http://www.gpoaccess.gov/fr/browse.html

 

The final rule establishes the initial installation and performance procedures that are required for evaluating the acceptability and ongoing performance of the PM CEMS.  Some affected sources include power generation units and hazardous waste incinerators.  There are several different types of PM CEMS technologies that are designed to sample continuously or by batch using in-situ or extractive sampling systems.  Each type has site specific advantages and therefore the type selected should be appropriate for the flue gas conditions at your source.  The most common types are described below:

 

PM CEMS Technology

 

Guidance for technology applications can be found in “Current Knowledge of Particulate Matter (PM) Continuous Emission Monitoring”  EPA-454/R-00-039, September 2000.  The following is a description of the three different measurement technology principles:

 

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Light Scattering – An emitted light beam passes through a defined sample volume.  PM causes incident light scattering which is focused by a detector and converted into an electrical output.  A second detector receives a portion of the scattered light and makes an adjustment for change in emitted power.  Used for continuous sampling.

 

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Beta Gauge - PM mass density is measured using the technique of Beta attenuation.  A small Beta source is coupled to a sensitive detector which counts the Beta particles.  As the mass of particles increases the Beta count is reduced.  The relationship between the decrease in count and the particulate mass is computed according to a known equation.  Used when batch sampling is required.

 

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Acoustic Energy - Shock waves caused by the impact of particles with a probe inserted into the flow are used to measure the particulate concentration.  The number and energy of each impact coupled with knowledge of the flow velocity, allows calculation of the particulate mass.  Used for continuous sampling.

 

Performance Specification 11 (PS-11)

 

Initial PA CEMS Criteria

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The PM CEMS must pass 7-day zero and upscale drift checks (No greater than 2%, zero reference is between 0-20% and upscale reference is between 50-100% of the PM CEMS response range).

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If using sample volumes, a sample volume check must be completed and passed daily.

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Any auxiliary monitors needed to convert data must meet calibration drift (No greater than 2%).

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If flue gas flow rates vary by more than 10%, the PM CEMS sample must be isokinetic.

 

PA CEMS Correlation Testing

 

PS-11 performance procedures are based on emission correlations of PM CEM responses and emission concentrations of a reference method.  This correlation is determined by conducting an initial correlation test.  Using the correlation test data, the correlation is developed by regression analysis following a linear, polynominal, logarithmic, exponential, or power correlation model.  Each model has its own set of equations.  The correlation data collected should be representative of the full range or normal operating conditions of the source if the range of operation does vary for that source.  A general summary of the criteria for correlation testing are as follows:

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Minimum of 15 and maximum of 20 manual reference methods are conducted over a full range of PM CEMS responses.

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Additional testing can be required if a source meets criteria outlined in Section 8.8.

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Reference method test runs can be less than 60 minutes in duration (e.g. 20 minutes).

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3 runs or 20% of the total runs must be at 3 PM concentration levels (0-50%, 25-75%, or 50-100% of the maximum flue gas PM concentration).

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Sampling location must meet USEPA Method 1 criteria.

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Reference method sampling will follow USEPA Methods 5, 5I, or 17.

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The correlation model used is dependant on performance criteria for each model outlined in Section 13.2.

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For batch sampling, the response time (or cycle time) must be no longer than 15 minutes.  The delay between the end of sampling and sample analysis reporting must be no greater than 3 minutes.  Sampling time must be no less than 30% of the cycle time.

Procedure 2

 

Periodic evaluations of the PM CEMS using a combination of various quarterly audits and daily calibration procedures will ensure that the PM CEMS data quality is maintained.  Sources must comply with these quality control and quality assurance measures immediately following successful completion of the correlation testing.  A general summary of daily and quarterly procedures are described below:

 

Daily

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Zero and upscale drift checks (Adjust when drift exceeds 4% for 5 consecutive days or 8% for 1 day).

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Sample volume checks (Adjust when error exceeds 10% for 5 consecutive days or 20% for 1 day).

Quarterly

 

An Absolute Correlation Audit (ACA) and Sample Volume Audit (SCA) must be conducted once per calendar quarter no closer than 2 months apart.  A Response Correlation Audit (RCA) or a Relative Response Audit (RRA) can be conducted in place of an ACA.  Key points from these audit procedures are summarized below:

 

ACA

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Challenge the PM CEMS 3 times with each of a 0-20, 40-60, and 70-100 audit standard (Use a separate standard for audit points 1, 2, and 3).

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In compliance if below +/-10% of the average audit value or 7.5% of the standard.

 SVA

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Independently measure the volume of each batch cycle or time period with a calibrated device on a consistent temperature, pressure, and moisture basis.

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3 measurements for batch extractive monitors.

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Three, 20-minute periods for continuous extractive monitors.

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In compliance if within +/- 5% of the average sample volume audit value.

 RCA

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Conducted in frequencies specified in the applicable permit.

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May be conducted in place of a RRA.

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Conduct an SVA prior to testing.

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Conduct testing the same as the correlation test except using only 12 test runs.

·     In compliance if 75% of data points are within 25% of the correlation regression line and or 9 of the 12 data points are within the output range used to develop the correlation curve.  For all 12 data points, the PM CEMS response value can be no greater than the greatest response used to develop the correlation curve.

 

RRA

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Conducted in frequencies specified in the applicable permit.

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Conduct an SVA prior to testing.

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Collect 3 simultaneous reference method PM and PM CEMS measurements.

·     In compliance if 2 of the 3 PM CEMS and Reference Method measurements fall within 25% of the correlation regression line and 2 of the 3 data points are within the output range used to develop the correlation curve.  For all 3 data points, the PM CEMS response value can be no greater than the greatest response used to develop the correlation curve.

 

REPORTING

 

Report all drift and accuracy data of any quarterly audit along with all emissions report data in a Data Assessment Report (DAR).  Keep audit, emission, and calibration data for a period of 5 years.

 

  Author:  Matthew Gregory, Project Scientist

  Date:  02/04/04

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